Both "take them to school" and "takes them to school" can be correct, but it depends on the context and subject-verb agreement.
1. "Take them to school" is in the imperative form, which is used to give a command or make a request. Example: "Please take them to school."
2. "Takes them to school" is in the present simple tense and agrees with a third person singular subject (he, she, it). Example: "She takes them to school every morning."
So, it depends on how you want to use the phrase and the subject of the sentence.
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